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Polymer rheology simulations at the meso- and macroscopic scale

机译:在中观和宏观尺度上的聚合物流变学模拟

摘要

We show that simulations of polymer rheology at a fluctuating mesoscopicscale and at the macroscopic scale where flow instabilities occur can beachieved at the same time with dissipative particle dynamics (DPD) technique.}We model the visco-elasticity of polymer liquids by introducing a finitefraction of dumbbells in the standard DPD fluid. The stretching and tumblingstatistics of these dumbbells is in agreement with what is known for isolatedpolymers in shear flows. At the same time, the model exhibits behaviourreminiscent of drag reduction in the turbulent state: as the polymer fractionincreases, the onset of turbulence in plane Couette flow is pushed to higherReynolds numbers. The method opens up the possibility to model nontrivialrheological conditions with ensuing coarse grained polymer statistics.
机译:我们显示了在波动的介观尺度和宏观尺度上发生流动不稳定性的聚合物流变学模拟可以通过耗散粒子动力学(DPD)技术同时实现。}我们通过引入有限分数来模拟聚合物液体的粘弹性标准DPD液体中的哑铃。这些哑铃的拉伸和翻滚统计与在剪切流中分离聚合物的已知一致。同时,该模型在湍流状态下表现出减阻作用:随着聚合物分数的增加,平面库埃特流中湍流的发生被推到更高的雷诺数。该方法提供了通过随后的粗粒聚合物统计来对非琐流变条件进行建模的可能性。

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